Customization: | Available |
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CAS No.: | 63148-57-2 |
Formula: | C7h22o2si3 |
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Product Name | Poly(methylhydrosiloxane) |
CAS: | 63148-57-2 |
MF: | C7H22O2Si3 |
MW: | 222.5 |
EINECS: | 613-152-3 |
Melting point | <-60°C |
Boiling point | 142 °C(lit.) |
Density | 1.006 g/mL at 25 °C (lit.) |
Vapor pressure | 38 hPa (20 °C) |
Refractive index | n20/D 1.382(lit.) |
Fp | 204 °C |
Storage temp. | Store below +30°C. |
Solubility | Soluble in most ethereal, chlorinated, or hydrocarbon solvents as well as EtOH, i-PrOH, warm DMF, and warm NMP; insoluble in MeOH, DMSO, acetonitrile, and water |
Specific Gravity | 0.98 |
PH | 7 (H2O) |
Water Solubility | Not miscible or difficult to mix in water. |
CAS DataBase Reference | 63148-57-2 |
Packing: | 200L/Brum or 1000L/IBC |
Application: Polymethylhydrosiloxane(PMHS) is an easily handled,inexpensive,non-toxic,and mild reducing agent. PMHS is attractive as a substitute for more expensive or hazardous silanes or siloxanes and as the stoichiometric reductant in catalytic organotin-mediated processes. It can be cross linked by metal catalyst at low temperature to form waterproof membrane. It is used as waterproof agent of textile, glass, pottery, paper, leather, metal, cement and marble etc, especially in textile waterproof. It is used as insulator and cross linker of paper. Poly(methylhydrosiloxane) is used in the reduction of esters to alcohols, catalyzed by a combination of titanocene dichloride and either n-BuLi or EtMgBr. It is a safer alternative to triethoxysilane, B22063, for reduction of phosphine oxides to phosphines, catalyzed by Ti(O-i-Pr)4. It is also used in greener amine synthesis by reductive amination as an alternative to borohydrides.